Lambda for max. power

Actually this is a karting question but I can't seem to get the answer anywhere.
The lambda for max. power using petrol is about 0.86. (Karts don't have to worry about pollution regulations...yet)
The question is: Does the max. power lambda change significantly with temperature and pressure?
If it does, are there any formulas which would allow me to calculate the max. power lambda for temperature T1, pressure P1 if I know the lambda for temperature T2, pressure P2?
I was told that the lambda = 0.86 comes from the fact that not all the full is burnt in the combustion chamber (in a 2-stroke at least) and it is not possible 100% combustion because, under normal engine conditions, the shape of the molecules in the petrol don't let the oxygen molecules get at the carbon/hydrogen atoms. Does anyone know if this is true?
Does anyone have an explanation of where the 0.86 comes from (especially if the above is not true)?
The lambda for max. power using petrol is about 0.86. (Karts don't have to worry about pollution regulations...yet)
The question is: Does the max. power lambda change significantly with temperature and pressure?
If it does, are there any formulas which would allow me to calculate the max. power lambda for temperature T1, pressure P1 if I know the lambda for temperature T2, pressure P2?
I was told that the lambda = 0.86 comes from the fact that not all the full is burnt in the combustion chamber (in a 2-stroke at least) and it is not possible 100% combustion because, under normal engine conditions, the shape of the molecules in the petrol don't let the oxygen molecules get at the carbon/hydrogen atoms. Does anyone know if this is true?
Does anyone have an explanation of where the 0.86 comes from (especially if the above is not true)?